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Ross Barkley spurned a chance to equalise by missing a penalty three minutes from time as Chelsea lost to Valencia in the Champions League.
Valencia players are on a self-imposed silence heading into Tuesday's Champions League opener at Chelsea as a sign of protest.
Barcelona made short work of Valencia in a 5-2 win at the Camp Nou with an injured Lionel Messi looking on from the sidelines.
Marcelino has said he is "absolutely certain" that winning the Copa del Rey last season triggered his sacking as Valencia coach this week.
Marcelino has been sacked as Valencia coach with Albert Celades hired as a replacement, the Spanish La Liga club said on Wednesday.
Real Madrid will face Paris Saint-Germain in the Champions League group stage this season.
Barcelona have reached an agreement with Valencia on Thursday over the signing of Brazilian goalkeeper Neto for €26 million plus €9m in add-ons.
Barcelona have confirmed the sale of Andre Gomes to Everton for €25 million, while Jasper Cillessen is in Valencia ahead of a €30m transfer.
Andre Gomes and Jasper Cillessen are both set to complete moves away from Barcelona before the end of the week, sources have told ESPN FC.
Manchester United are in talks to sell Matteo Darmian, sources have told ESPN FC.
Barcelona's hopes of a domestic double were extinguished Saturday after a 2-1 defeat to Valencia in the Copa del Rey final.
Twenty-three football fans were arrested in Seville following disturbances which left five police officers injured ahead of the Copa del Rey final.
Barcelona eye a fifth straight Copa del Rey title, and Valencia seek their first trophy since 2008. Sid Lowe sets up the 117th Copa del Rey final.
Valencia beat Getafe to fourth place in La Liga and secured Champions League football for the second year in a row.
Valencia took control of the battle for the final Champions League qualifying place in La Liga by beating Alaves 3-1 to climb above Getafe.
Pierre-Emerick Aubameyang scored a hat trick as Arsenal beat Valencia 4-2 on Thursday and 7-3 on aggregate in their Europa League semifinal.
Scoring twice and adding a pair of assists as your side desperately chases a Champions League place is reason enough to top Player Power Rankings.
A Valencia spokesman told ESPN FC they opened disciplinary proceedings against an unnamed fan with a view to having his club membership taken away.
Huesca were relegated from La Liga on Sunday after they were hammered 6-2 by a rampant Valencia.
Arsenal have condemned the racist behaviour of a section of Valencia fans who were filmed making monkey gestures and Nazi salutes on Thursday night.
Arsenal showed no sign of solving the issues that have plagued them of late, but that mattered little as their world-class forwards rolled Valencia.
Alexandre Lacazette scored two early goals to give Arsenal a 3-1 win over Valencia in the first leg of the Europa League semifinals.
Valencia's hopes of sneaking into the top four in La Liga were severely dented with a limp 1-0 defeat at home to Eibar on Sunday.